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Abstract

Compressional and shear wave velocities of polycrystalline stishovite (SiO2) have been measured at simultaneous high pressures and temperatures up to 14.5 GPa and 800°C. By fitting velocities to the finite strain equations, the elastic moduli and density were determined to be KS0 = 306.6(46) GPa, KS′ = 4.92(10), ∂KS/∂T = −0.024(1) GPa/K, G0 = 229.0(34) GPa, G′ = 1.07(10), ∂G/∂T = −0.017(1) GPa/K, ρ0 = 4.287(2) g/cm3. Our modeling suggested that, in the eclogite, coesite-stishovite transition can increase P and S wave velocities by 2.4% and 3.5%, respectively. A comparison between geophysical observations and our model shows that the coesite-stishovite phase transition in the eclogite can potentially be responsible for the occurrence of the X discontinuity beneath Hawaii. In addition, our current results suggest an eclogite-rich layer between 340 and 450 km depth beneath Hawaii. The eclogite concentration at the top and bottom of the layer is 41–55 vol% and >77 vol%, respectively.

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