Rapid Microwave-Assisted Synthesis of ZnIn2S4 Nanosheets for Highly Efficient Photocatalytic Hydrogen Production

In this study, a facile and rapid microwave-assisted synthesis method was used to synthesize In₂S₃ nanosheets, ZnS nanosheets, and ZnIn₂S₄ nanosheets with sulfur vacancies. The two-dimensional semiconductor photocatalysts of ZnIn₂S₄ nanosheets were characterized by XRD, FESEM, BET, TEM, XPS, UV–vis diffuse reflectance, and PL spectroscopy. The ZnIn₂S₄ with sulfur vacancies exhibited an evident energy bandgap value of 2.82 eV, as determined by UV–visible diffuse reflectance spectroscopy, and its energy band diagram was obtained through the combination of XPS and energy bandgap values. ZnIn₂S₄ nanosheets exhibited about 33.3 and 16.6 times higher photocatalytic hydrogen production than In₂S₃ nanosheets and ZnS nanosheets, respectively, under visible-light irradiation. Various factors, including materials, sacrificial reagents, and pH values, were used to evaluate the influence of ZnIn₂S₄ nanosheets on photocatalytic hydrogen production. In addition, the ZnIn₂S₄ nanosheets revealed the highest photocatalytic hydrogen production from seawater, which was about 209.4 and 106.7 times higher than that of In₂S₃ nanosheets and ZnS nanosheets, respectively. The presence of sulfur vacancies in ZnIn₂S₄ nanosheets offers promising opportunities for developing highly efficient and stable photocatalysts for photocatalytic hydrogen production from seawater under visible-light irradiation.