@article{Functionalization:1608, recid = {1608}, author = {Xu, Yan}, title = {Transition Metal-Catalyzed Functionalization of C−H and C−C Bonds}, publisher = {The University of Chicago}, school = {Ph.D.}, address = {2018-08}, pages = {989}, abstract = {In this dissertation, the development of several novel organic synthetic methods featuring the functionalization of C−H and C−C bonds was described by using transition metal catalysis, including the Pd-catalyzed β sp3 C−H sulfonyloxylation of alcohols, the Pd-catalyzed γ sp3 C−H arylation of free primary amines, the Pd-catalyzed α-arylation of cyclopentanones, the Rh-catalyzed β sp3 C–H functionalization of ketones, and the Ir-catalyzed C−C cleavage of unstrained ketones driven by aromatization.}, url = {http://knowledge.uchicago.edu/record/1608}, doi = {https://doi.org/10.6082/uchicago.1608}, }